Musnad Ahmad ibn Hanbal: Book 5, Hadith 610
It was narrated from ‘Ali (رضي الله عنه) that He was asked about the (voluntary) prayers of the Messenger of Allah (ﷺ) during the day. He said: He used to pray sixteen rak`ahs, When the sun was as high there as it is at the time of ‘Asr there, he would pray two rak’ahs. When the sun was as high there as it is at the time of Zuhr there, he would pray two rak`ahs, He would pray four rak`ahs before Zuhr and two rak`ahs after Zuhr, and he would pray four rak`ahs before ʻAsr.
Musnad Ahmad ibn Hanbal: Book 5, Hadith 610
The above hadith is from the Musnad Ahmad ibn Hanbal collection of hadiths. The Musnad of Imam Ahmad ibn Hanbal is a foundational work in Islamic hadith literature, highly valued for its comprehensive nature. Its most defining feature is its organizational method; it categorizes hadiths based on the companion of the Prophet who first reported them, with a dedicated section for each. This structure provides a unique window into the practices and sayings of the Prophet as witnessed and related by his diverse companions. Although the Musnad is held in extremely high regard and contains many authentic narrations, it is important to note that, due to its encyclopedic aim of collecting available reports, it also contains some hadiths with weaker chains of transmission that are subject to scholarly scrutiny.
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For more Hadith in Book 5: Musnad ‘Ali Ibn Abi Talib